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ChemInform Abstract: Interactions of a Diarylmagnesium Compound with Cryptands and Crown Ethers: Formation of Ar3Mg‐, ArMg(cryptand)+, and Threaded Ar2Mg(crown ether).

Herman G. Richey, Diana M. Kushlan

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Abstract

Abstract On reaction of a 2:1 mixture of solid Mg(tol)2 (tol: p‐tolyl) and 221‐cryptand the 1H NMR spectrum indicates the presence of a complex (Mg(tol)(221‐cryptand))+ and (Mg(tol)3)‐, a type of ion not having been observed previously.

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Abstract On reaction of a 2:1 mixture of solid Mg(tol)2 (tol: p‐tolyl) and 221‐cryptand the 1H NMR spectrum indicates the presence of a complex (Mg(tol)(221‐cryptand))+ and (Mg(tol)3)‐, a type of ion not having been observed previously.

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Available abstract

Abstract On reaction of a 2:1 mixture of solid Mg(tol)2 (tol: p‐tolyl) and 221‐cryptand the 1H NMR spectrum indicates the presence of a complex (Mg(tol)(221‐cryptand))+ and (Mg(tol)3)‐, a type of ion not having been observed previously.

Key concepts: Cryptand, Chemistry, Crown ether, Ether, Medicinal chemistry, Stereochemistry, Ion, Organic chemistry

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ChemInform Abstract: Interactions of a Diarylmagnesium Compound with Cryptands and Crown Ethers: Formation of Ar3Mg‐, ArMg(cryptand)+, and Threaded Ar2Mg(crown ether). — Research Paper | ScholarLens