2007•Unpublished venueRequires access

Catalytic CH Amination with Nitrenes

Philippe Dauban, Robert H. Dodd

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Abstract

This chapter contains sections titled: Introduction Historical Overview Hypervalent Iodine-Mediated CH Amination Intramolecular CH Amination From NH2 Carbamates From NH2 Sulfamates From Other Nitrogen Functionalities Intermolecular CH Amination General Scope and Limitations Recent Major Improvements Other Nitrene Precursors for CH Amination Azides Haloamines Carbamate Derivatives Amination of Aromatic CH Bonds Applications in Total Synthesis Application of Intramolecular CH Amination with Carbamates Application of Intramolecular CH Amination with Sulfamates Application of Intermolecular CH Amination Conclusions

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What this paper is about

This chapter contains sections titled: Introduction Historical Overview Hypervalent Iodine-Mediated CH Amination Intramolecular CH Amination From NH2 Carbamates From NH2 Sulfamates From Other Nitrogen Functionalities Intermolecular CH Amination General Scope and Limitations Recent Major Improvements Other Nitrene Precursors for CH Amination Azides Haloamines Carbamate Derivatives Amination of Aromatic CH Bonds Applications in Total Synthesis Application of Intramolecular CH Amination with Carbamates Application of Intramolecular CH Amination with Sulfamates Application of Intermolecular CH Amination Conclusions

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Available abstract

This chapter contains sections titled: Introduction Historical Overview Hypervalent Iodine-Mediated CH Amination Intramolecular CH Amination From NH2 Carbamates From NH2 Sulfamates From Other Nitrogen Functionalities Intermolecular CH Amination General Scope and Limitations Recent Major Improvements Other Nitrene Precursors for CH Amination Azides Haloamines Carbamate Derivatives Amination of Aromatic CH Bonds Applications in Total Synthesis Application of Intramolecular CH Amination with Carbamates Application of Intramolecular CH Amination with Sulfamates Application of Intermolecular CH Amination Conclusions

Key concepts: Amination, Nitrene, Chemistry, Intramolecular force, Hypervalent molecule, Intermolecular force, Organic chemistry, Combinatorial chemistry

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