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Evaluating BP Solar's Mono2 ™ material: Lifetime and cell electrical data

Nathan Stoddard, Rubin Sidhu, Joe Creager, Soham Dey, B. Kinsey, Lisa Maisano, Calista Phillips, Roger Clark, James M. Zahler, Xianqing Xie, Tingbin Wu, Qing-Tang Jiang

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Abstract

Single crystal Silicon has been produced using a cast-in-place process usually used for multicrystalline ingot production. This Mono2 TMmaterial produces higher cell efficiencies compared to multi crystalline silicon material with the same average minority carrier lifetime. Profiles of lifetime through the height of the brick and across the ingot demonstrate rough equivalency in bulk lifetime between Mono2 TMand multi material. However, the standard deviation of lifetime in wafers is smaller for the Mono2 TMmaterial. This quality difference accounts for about half of the potential efficiency gain in Mono2 TMmaterial, while the rest of the gain, primarily in Jsc, is derived from the ability to form pyramidal light trapping texture on the (100) surface. Minority carrier lifetime data is compared with cell electrical data from the same collection of ingot positions. Open circuit voltage and short circuit current correlate well to some degree with bulk lifetime, while fill factor is independent both of bulk lifetime and position in the ingot.

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What this paper is about

Single crystal Silicon has been produced using a cast-in-place process usually used for multicrystalline ingot production. This Mono2 TMmaterial produces higher cell efficiencies compared to multi crystalline silicon material with the same average minority carrier lifetime. Profiles of lifetime through the height of the brick and across the ingot demonstrate rough equivalency in bulk lifetime between Mono2 TMand multi material. However, the standard deviation of lifetime in wafers is smaller for the Mono2 TMmaterial. This quality difference accounts for about half of the potential efficiency gain in Mono2 TMmaterial, while the rest of the gain, primarily in Jsc, is derived from the ability to form pyramidal light trapping texture on the (100) surface. Minority carrier lifetime data is compared with cell electrical data from the same collection of ingot positions. Open circuit voltage and short circuit current correlate well to some degree with bulk lifetime, while fill factor is independent both of bulk lifetime and position in the ingot.

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Available abstract

Single crystal Silicon has been produced using a cast-in-place process usually used for multicrystalline ingot production. This Mono2 TMmaterial produces higher cell efficiencies compared to multi crystalline silicon material with the same average minority carrier lifetime. Profiles of lifetime through the height of the brick and across the ingot demonstrate rough equivalency in bulk lifetime between Mono2 TMand multi material. However, the standard deviation of lifetime in wafers is smaller for the Mono2 TMmaterial. This quality difference accounts for about half of the potential efficiency gain in Mono2 TMmaterial, while the rest of the gain, primarily in Jsc, is derived from the ability to form pyramidal light trapping texture on the (100) surface. Minority carrier lifetime data is compared with cell electrical data from the same collection of ingot positions. Open circuit voltage and short circuit current correlate well to some degree with bulk lifetime, while fill factor is independent both of bulk lifetime and position in the ingot.

Key concepts: Carrier lifetime, Ingot, Wafer, Silicon, Materials science, Physics, Topology (electrical circuits), Analytical Chemistry (journal)

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