F. Gini, B. Hessen, Ben L. Feringa, Adriaan J. Minnaard
Abstract
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The complex formed from Pd(CH(3)CN)(4)(BF(4))(2) and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.
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The complex formed from Pd(CH(3)CN)(4)(BF(4))(2) and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.
Key concepts: Enantioselective synthesis, Conjugate, Palladium, Catalysis, Chemistry, Combinatorial chemistry, Stereochemistry, Organic chemistry