1969Canadian Journal of ChemistryOpen access

Abstraction of hydrogen from hydrogen sulfide by methyl radicals

Peter Gray, Alan A. Herod, L. J. Leyshon

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Abstract

The methyl radical attack on H2S has been investigated briefly using azomethane as the radical source. The results indicate that the previous rate-constants for the abstraction reaction are too high and that CF3 radicals may react with H2S faster than CH3 radicals.

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What this paper is about

The methyl radical attack on H2S has been investigated briefly using azomethane as the radical source. The results indicate that the previous rate-constants for the abstraction reaction are too high and that CF3 radicals may react with H2S faster than CH3 radicals.

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Available abstract

The methyl radical attack on H2S has been investigated briefly using azomethane as the radical source. The results indicate that the previous rate-constants for the abstraction reaction are too high and that CF3 radicals may react with H2S faster than CH3 radicals.

Key concepts: Chemistry, Radical, Hydrogen atom abstraction, Hydrogen sulfide, Photochemistry, Abstraction, Hydrogen, Methyl radical

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