2004•Medical Entomology and ZoologyRequires access

Advanced free radical reactions for organic synthesis

秀雄東郷

Abstract

What are free radicals. Functional group conversion. Intramolecular radical cyclizations. Intermolecular radical addition reactions. Alkylation of aromatics. Intramolecular hydrogen-atom abstraction. Synthetic uses of free radicals for nucleosides and sugars: Barton-McCombie reaction. Barton decarboxylation reaction with N-hydroxy-2-thiopyridone. Free radical reactions with metal hydrides. Stereochemistry in free radical reactions. Free radicals related to biology. Free radicals for green chemistry.

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Available abstract

Key concepts: Radical, Chemistry, Radical substitution, Radical disproportionation, Decarboxylation, Intramolecular force, Free-radical reaction, Beta scission