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1983•Chemistry LettersOpen access

REACTIONS OF ALLYLSILANES WITH α-CHLORO ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS

Hideki Sakurai, Yasuyuki Sakata, Akíra Hosomi

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Abstract

Abstract Iodotrimethylsilane and trimethylsilyl triflate activate selectively the C–Cl bond rather than the C–O bond of α-chloro ethers and catalyze the allylation with allylsilanes to give the corresponding homoallyl ethers effectively in good yield.

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Abstract Iodotrimethylsilane and trimethylsilyl triflate activate selectively the C–Cl bond rather than the C–O bond of α-chloro ethers and catalyze the allylation with allylsilanes to give the corresponding homoallyl ethers effectively in good yield.

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Available abstract

Abstract Iodotrimethylsilane and trimethylsilyl triflate activate selectively the C–Cl bond rather than the C–O bond of α-chloro ethers and catalyze the allylation with allylsilanes to give the corresponding homoallyl ethers effectively in good yield.

Key concepts: Chemistry, Trimethylsilyl trifluoromethanesulfonate, Trimethylsilyl, Trifluoromethanesulfonate, Catalysis, Medicinal chemistry, Organic chemistry

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REACTIONS OF ALLYLSILANES WITH α-CHLORO ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS — Research Paper | ScholarLens