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Convenient Synthesis of Monoselenoacetals from Acetals with Phenyl Trimethylsilyl Selenide

Makoto Sakakibara, Kazuhiro Katsumata, Yoshihiko Watanabe, Takeshi Toru, Yoshio Ueno

Abstract

All articles of this category Monoselenoacetals can be efficiently prepared from acetals by treatment with phenyl trimethylsilyl selenide in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate. This procedure also effects the transformation of acetyl glucoside into selenoglucoside.

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Key concepts: Chemistry, Trimethylsilyl, Trimethylsilyl trifluoromethanesulfonate, Selenide, Trifluoromethanesulfonate, Organic chemistry, Catalysis, Acetal