Selection of Blended Solvents for CO2 Absorption from Coal-Fired Flue Gas. Part 1: Monoethanolamine (MEA)-Based Solvents
Dechen Zhu, Mengxiang Fang, Lv Zhong, Zhen Wang, Zhongyang Luo
Abstract
Dechen Zhu, Mengxiang Fang, Lv Zhong, Zhen Wang, Zhongyang Luo
Abstract
Solvent selection is the potential breakthrough for the chemical absorption method to capture CO 2 from coal-fired flue gas. A total of 16 kinds of selected monoethanolamine (MEA)-based solvents were assessed by absorption at 40 °C up to 12 kPa CO 2 partial pressure and desorption at 100 °C down to 1.0 kPa CO 2 partial pressure. Results showed that the 20% MEA + 10% diethylenetriamine (DETA) system maintains the highest average absorption rates and reaches the highest loading of 0.556 kg of CO 2 /kg of solute during all of the tested systems. The absorption capacity of the 20% MEA + 10% DETA system is increased to 53%, and the corresponding average removal efficiency is enhanced more than 31% compared to 30% MEA solution. Furthermore, there is only a slight difference between the regeneration performance of the 20% MEA + 10% DETA system and that of the 30% MEA solution.
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Solvent selection is the potential breakthrough for the chemical absorption method to capture CO 2 from coal-fired flue gas. A total of 16 kinds of selected monoethanolamine (MEA)-based solvents were assessed by absorption at 40 °C up to 12 kPa CO 2 partial pressure and desorption at 100 °C down to 1.0 kPa CO 2 partial pressure. Results showed that the 20% MEA + 10% diethylenetriamine (DETA) system maintains the highest average absorption rates and reaches the highest loading of 0.556 kg of CO 2 /kg of solute during all of the tested systems. The absorption capacity of the 20% MEA + 10% DETA system is increased to 53%, and the corresponding average removal efficiency is enhanced more than 31% compared to 30% MEA solution. Furthermore, there is only a slight difference between the regeneration performance of the 20% MEA + 10% DETA system and that of the 30% MEA solution.
Key concepts: Diethylenetriamine, Flue gas, Chemistry, Absorption (acoustics), Solvent, Desorption, Coal, Chemical engineering