A New Route to 3H-1,5-Benzodiazepines and Heterocylic Ketene Aminals from Benzoyl Substituted Ketene Dithioacetals and Diamines
Zhi‐Tang Huang, Mei‐Xiang Wang
Abstract
Zhi‐Tang Huang, Mei‐Xiang Wang
Abstract
All articles of this category Heterocyclic ketene aminals 5 or 3 H -1,5-benzodiazepines 4 were obtained from the reaction of benzoyl substituted ketene dithioacetals 1 with various diamines 2 . The mechansim of formation of these two different products are discussed.
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All articles of this category Heterocyclic ketene aminals 5 or 3 H -1,5-benzodiazepines 4 were obtained from the reaction of benzoyl substituted ketene dithioacetals 1 with various diamines 2 . The mechansim of formation of these two different products are discussed.
Key concepts: Ketene, Chemistry, Aminal, Wolff rearrangement, Organic chemistry, Medicinal chemistry