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Direct calculation of fluctuation formulae in the microcanonical ensemble

John R. Ray, H. W. Graben

Open publisher page 64 citations

Abstract

We present simple derivations of the classical microcanonical ensemble formulae for fluctuations which involve the kinetic energy and microscopic pressure function. The new derivations, which confirm earlier results of Lebowitz et al. [1] and Cheung [2], proceed in a direct way from basic microcanonical ensemble theory without recourse to fluctuation expressions of other ensemble theories. The method developed is applicable to shell ensembles in general.

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What this paper is about

We present simple derivations of the classical microcanonical ensemble formulae for fluctuations which involve the kinetic energy and microscopic pressure function. The new derivations, which confirm earlier results of Lebowitz et al. [1] and Cheung [2], proceed in a direct way from basic microcanonical ensemble theory without recourse to fluctuation expressions of other ensemble theories. The method developed is applicable to shell ensembles in general.

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Available abstract

We present simple derivations of the classical microcanonical ensemble formulae for fluctuations which involve the kinetic energy and microscopic pressure function. The new derivations, which confirm earlier results of Lebowitz et al. [1] and Cheung [2], proceed in a direct way from basic microcanonical ensemble theory without recourse to fluctuation expressions of other ensemble theories. The method developed is applicable to shell ensembles in general.

Key concepts: Microcanonical ensemble, Canonical ensemble, Statistical ensemble, Statistical physics, Simple (philosophy), Ensemble average, Physics, Kinetic energy

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