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2013•Organic & Biomolecular ChemistryRequires access

Thermal induced intramolecular [2 + 2] cycloaddition of allene-ACPs

Kai Chen, Run Sun, Qin Xu, Yin Wei, Min Shi

Open publisher page 36 citations

Abstract

A facile synthetic method for preparation of bicyclo[4.2.0] nitrogen heterocycles has been developed via a thermal induced intramolecular [2 + 2] cycloaddition reaction of allene-ACPs. The DFT calculations indicate that this intramolecular cycloaddition proceeds in a concerted manner and a strained small ring is essential.

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What this paper is about

A facile synthetic method for preparation of bicyclo[4.2.0] nitrogen heterocycles has been developed via a thermal induced intramolecular [2 + 2] cycloaddition reaction of allene-ACPs. The DFT calculations indicate that this intramolecular cycloaddition proceeds in a concerted manner and a strained small ring is essential.

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OpenAlex reports 36 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

A facile synthetic method for preparation of bicyclo[4.2.0] nitrogen heterocycles has been developed via a thermal induced intramolecular [2 + 2] cycloaddition reaction of allene-ACPs. The DFT calculations indicate that this intramolecular cycloaddition proceeds in a concerted manner and a strained small ring is essential.

Key concepts: Cycloaddition, Intramolecular force, Chemistry, Allene, Ring (chemistry), Bicyclic molecule, Photochemistry, Computational chemistry

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