1,3-Bis(phenylsulfonyl)allene as a New Reagent for Cycloaddition Methodology
James R. Bull, Nicholas S. Desmond-Smith, Steven J. Heggie, Roger Hunter, Feng-Chang Tien
Abstract
James R. Bull, Nicholas S. Desmond-Smith, Steven J. Heggie, Roger Hunter, Feng-Chang Tien
Abstract
All articles of this category 1,3-Bis(phenylsulfonyl)allene 2 has been synthesised as a new reagent for cycloaddition methodology. In contrast to phenylsulfonylallene 1 , thermal reaction of 2 with substituted 1,3-dienes gave both [2 + 2] as well as [2 + 4] cycloaddition products. sulfonylallene - intermolecular [2 + 2] and [2 + 4] cycloaddition
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All articles of this category 1,3-Bis(phenylsulfonyl)allene 2 has been synthesised as a new reagent for cycloaddition methodology. In contrast to phenylsulfonylallene 1 , thermal reaction of 2 with substituted 1,3-dienes gave both [2 + 2] as well as [2 + 4] cycloaddition products. sulfonylallene - intermolecular [2 + 2] and [2 + 4] cycloaddition
Key concepts: Allene, Cycloaddition, Chemistry, Reagent, Combinatorial chemistry, Organic chemistry, Medicinal chemistry, Catalysis