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1970•Journal of Polymer Science Part A-1 Polymer ChemistryRequires access

Irradiation of terephthalophenone in isopropyl alcohol

DONALD E. PEARSON, P. D. Thiemann

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Abstract

Abstract Irradiation of terephthalophenone in isopropyl alcohol gave a bright yellow‐colored intermediate which decayed rather rapidly. The products were complex and depended upon the mode of irradiation. They ranged from a mixed polymer I to a dimer II. I consisted of about 5 terephthalophenone units capped with hydrogen or isopropyl alcohol radicals or terminated by cyclization. II, the dimer, was capped by hydrogen atoms.

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Abstract Irradiation of terephthalophenone in isopropyl alcohol gave a bright yellow‐colored intermediate which decayed rather rapidly. The products were complex and depended upon the mode of irradiation. They ranged from a mixed polymer I to a dimer II. I consisted of about 5 terephthalophenone units capped with hydrogen or isopropyl alcohol radicals or terminated by cyclization. II, the dimer, was capped by hydrogen atoms.

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Available abstract

Abstract Irradiation of terephthalophenone in isopropyl alcohol gave a bright yellow‐colored intermediate which decayed rather rapidly. The products were complex and depended upon the mode of irradiation. They ranged from a mixed polymer I to a dimer II. I consisted of about 5 terephthalophenone units capped with hydrogen or isopropyl alcohol radicals or terminated by cyclization. II, the dimer, was capped by hydrogen atoms.

Key concepts: Isopropyl alcohol, Isopropyl, Irradiation, Dimer, Alcohol, Chemistry, Radical, Photochemistry

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