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Influence of electron irradiation on hydrothermally grown zinc oxide single crystals

Lu Lu, C. K. So, Congyong Zhu, Qilin Gu, Changshu Li, S. Fung, Gerhard M Brauer, W. Anwand, W. Skorupa, C. C. Ling

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Abstract

The resistivity of hydrothermally grown ZnO single crystals increased from ∼10 3 cm to ∼10 6 cm after 1.8 MeV electron irradiation with a fluence of ∼10 16 cm -2 , and to ∼10 9 cm as the fluence increased to ∼10 18 cm -2 .Defects in samples were studied by thermally stimulated current (TSC) spectroscopy and positron lifetime spectroscopy (PLS).After the electron irradiation with a fluence of 10 18 cm -2 , the normalized TSC signal increased by a factor of ∼100.A Zn vacancy was also introduced by the electron irradiation, though with a concentration lower than expected.After annealing in air at 400 • C, the resistivity and the deep traps concentrations recovered to the levels of the as-grown sample, and the Zn vacancy was removed.

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The resistivity of hydrothermally grown ZnO single crystals increased from ∼10 3 cm to ∼10 6 cm after 1.8 MeV electron irradiation with a fluence of ∼10 16 cm -2 , and to ∼10 9 cm as the fluence increased to ∼10 18 cm -2 .Defects in samples were studied by thermally stimulated current (TSC) spectroscopy and positron lifetime spectroscopy (PLS).After the electron irradiation with a fluence of 10 18 cm -2 , the normalized TSC signal increased by a factor of ∼100.A Zn vacancy was also introduced by the electron irradiation, though with a concentration lower than expected.After annealing in air at 400 • C, the resistivity and the deep traps concentrations recovered to the levels of the as-grown sample, and the Zn vacancy was removed.

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Available abstract

The resistivity of hydrothermally grown ZnO single crystals increased from ∼10 3 cm to ∼10 6 cm after 1.8 MeV electron irradiation with a fluence of ∼10 16 cm -2 , and to ∼10 9 cm as the fluence increased to ∼10 18 cm -2 .Defects in samples were studied by thermally stimulated current (TSC) spectroscopy and positron lifetime spectroscopy (PLS).After the electron irradiation with a fluence of 10 18 cm -2 , the normalized TSC signal increased by a factor of ∼100.A Zn vacancy was also introduced by the electron irradiation, though with a concentration lower than expected.After annealing in air at 400 • C, the resistivity and the deep traps concentrations recovered to the levels of the as-grown sample, and the Zn vacancy was removed.

Key concepts: Fluence, Irradiation, Annealing (glass), Vacancy defect, Electrical resistivity and conductivity, Electron beam processing, Analytical Chemistry (journal), Zinc

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