1990Makromolekulare Chemie Macromolecular SymposiaRequires access

A comparison of theoretical predictions and experimental evidences of miscibility for poly(ethylene oxide)‐based blends

Sossio Cimmino, E. Martuscelli, Michele Saviano, Clara Silvestre

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Abstract

Abstract Mixtures of poly(ethylene oxide)/atactic poly(methyl methacrylate) (PEO/At‐PMMA) blends and poly(ethylene oxide)/poly(ethylene‐co‐vinylacetate) (PEO/EVAc‐1) blends were prepared by casting from a common solvent and were found miscible. The applications of the Solubility Parameter Theory, Patterson Theory and the Equation of State Theory of Flory are reported. The miscibility predictions obtained are discussed and compared to experimental miscibility evidence.

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Abstract Mixtures of poly(ethylene oxide)/atactic poly(methyl methacrylate) (PEO/At‐PMMA) blends and poly(ethylene oxide)/poly(ethylene‐co‐vinylacetate) (PEO/EVAc‐1) blends were prepared by casting from a common solvent and were found miscible. The applications of the Solubility Parameter Theory, Patterson Theory and the Equation of State Theory of Flory are reported. The miscibility predictions obtained are discussed and compared to experimental miscibility evidence.

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Available abstract

Abstract Mixtures of poly(ethylene oxide)/atactic poly(methyl methacrylate) (PEO/At‐PMMA) blends and poly(ethylene oxide)/poly(ethylene‐co‐vinylacetate) (PEO/EVAc‐1) blends were prepared by casting from a common solvent and were found miscible. The applications of the Solubility Parameter Theory, Patterson Theory and the Equation of State Theory of Flory are reported. The miscibility predictions obtained are discussed and compared to experimental miscibility evidence.

Key concepts: Miscibility, Ethylene oxide, Hildebrand solubility parameter, Materials science, Solubility, Oxide, Solvent, Thermodynamics

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