1934•The Journal of Chemical PhysicsRequires access

Analysis of Rotatory Dispersion Curves. II Configurationally Related Substituted Fatty Acids

Phoebus A. Levene, Alexandre Rothen

Abstract

The rotatory dispersion curves of substituted fatty acids of the types COOH |H–C–SH | R and COOH |H–C–SO3H | Rhave been measured in the visible and ultraviolet regions. The results are in harmony with the rule previously reported that in members of homologous series, the total rotation of consecutive members may differ in sign, but the signs of the partial rotations remain constant.

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Key concepts: Optical rotatory dispersion, Optical rotation, Homologous series, Chemistry, Specific rotation, Ultraviolet, Sign (mathematics), Dispersion (optics)