2015•Mendeleev CommunicationsRequires access

Synthesis of anionic peptide nucleic acid oligomers including γ-carboxyethyl thymine monomers

A. V. Dezhenkov, Maria V. Tankevich, Elena D. Nikolskaya, Igor P. Smirnov, Galina E. Pozmogova, Vitaly I. Shvets, Yu. G. Kirillova

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Abstract

Synthesis of a modified thymine monomer based on l-Glu, solid phase synthesis of anionic peptide nucleic acid (PNA) oligomers containing the modified monomer and optimization of the deblocking procedure and cleavage conditions of the PNA oligomers from resin are accomplished.

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Available abstract

Key concepts: Chemistry, Peptide nucleic acid, Monomer, Nucleic acid, Thymine, Combinatorial chemistry, Solid-phase synthesis, Cleavage (geology)