1997•Chinese Journal of ChemistryRequires access

Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium

Huaming Li, Xingkai Ye, Xiangguang Yang, Yue Wu

Abstract

Abstract The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)2/HQ/FePc wan investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexene was explored by means of UV‐VIS, IR., XPS spectroscopy and cyclic voltammetry, respectively. Based on the experimental results, the mechanism of the oxidation of cyclohexene catalysed by Pd(OAc)2/HQ/FePc was elucidated.

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Available abstract

Key concepts: Cyclohexanone, Chemistry, Cyclohexene, Acetonitrile, Aqueous solution, Catalysis, Cyclic voltammetry, Catalytic oxidation