2001•Huaxue Shijie (Chemical World)Requires access

Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compoound and Schiff Base

Peng Qing

Abstract

Cyclohexene was oxidized to cyclohexanone catalytically by Pd(NO 3) 2/Schiff base Fe(Ⅲ)/hydroquinone. Some factors influencing the activity of the catalyst were studied. Experimental results showed that in the catalyst sytstem, palladium compounds, water, acid, Schiff base and hydroquinone are necessary. The best reaction conditions are temprature, about 40℃; acid concentration, 75～80 mmol/L; hydroquinone concentration, 4～6 mmol/L.

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Key concepts: Cyclohexanone, Cyclohexene, Hydroquinone, Catalysis, Palladium, Chemistry, Schiff base, Base (topology)