Molybdenum mineralization in the ores of the Tigriny tin deposit (Primorye, Russia)

The molybdenum mineralization at the Tigriny tin deposit is considered for the first time in the light of possible recovery of Mo as a by-product of selective mining. It is established that Mo has a positive correlation with Bi and does not show a correlation with Sn, W, or Zn. The highest Mo grade (>0.1%) in the ore stockwork is related to hornfels near the exposed granite porphyry stock and decreases downward by an order of magnitude. At the level of adit 5, the most numerous quartz-molybdenite veinlets develop at a distance of 50–100 m from the granite porphyry stock. The molybdenite-quartz, pegmatoid, and autogreisen generations of molybdenum mineralization are related to different substages of the first ore stage. All these generations predated crystallization of wolframite, cassiterite, and other ore minerals. The formation temperature for each molybdenite generation was determined by homogenization of fluid inclusions in quartz and decrepitation of samples characterizing each molybdenite-bearing assemblage. These data allowed us not only to estimate the crystallization temperature of each molybdenite generation but also to establish that the molybdenite crystallized from a pneumatolytic-hydrothermal melt-solution at the early stage of the deposit formation. The molybdenum mineralization is genetically related to the granite porphyry stock. The structure of the quartz-molybdenum stockwork was studied to determine the clusters of quartz-molybdenite veinlets and establish their orientation. Molybdenite 1 occurs in variably oriented veinlets that make up a stockwork around the apical portion of the porphyry stock. Disseminations and pockets of molybdenites 2 and 3 are hosted in pegmatoid rocks, greisen, and greisenized granite porphyry. The density of the Tigriny stockwork varies from 0 to 40–50 quartz-molybdenite veinlets per 5 m. Their orientation and spatial distribution were studied in quantitative terms. The most promising targets for selective mining of molybdenite from the Tigriny deposit are the framework of the Minor porphyry stock and the apical portion of the Main stock. The Tigriny deposit demonstrates a clear relationship between ore formation and granitic magmatism.