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Synthesis and optical properties of transparent ZnO–Ga2O3–SiO2glass-ceramics embedded with cobalt-doped nanocrystals

Xiulan Duan, Dongsheng Yuan, Xiu Feng Cheng, Fapeng Yu, Zhiqiang Liu, Xiangze Zhang

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Abstract

Transparent ZnO–Ga 2 O 3 –SiO 2 glass-ceramics embedded with Co 2+ :ZnGa 2 O 4 nanocrystals were fabricated by the sol–gel method. X-ray diffraction, infrared spectroscopy and high-resolution transmission electron microscopy showed that the resulting material is composed of an amorphous silicate network and single-crystalline ZnGa 2 O 4 particles. Analysis of the absorption and luminescence properties indicates that Co ions are trapped in the crystalline phase and located in the tetrahedral sites in ZnGa 2 O 4 nanocrystals. The crystal field parameter D q of 418 cm −1 and the Racah parameters B of 761 cm −1 and C of 3424 cm −1 were determined for tetrahedral Co 2+ ions.

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What this paper is about

Transparent ZnO–Ga 2 O 3 –SiO 2 glass-ceramics embedded with Co 2+ :ZnGa 2 O 4 nanocrystals were fabricated by the sol–gel method. X-ray diffraction, infrared spectroscopy and high-resolution transmission electron microscopy showed that the resulting material is composed of an amorphous silicate network and single-crystalline ZnGa 2 O 4 particles. Analysis of the absorption and luminescence properties indicates that Co ions are trapped in the crystalline phase and located in the tetrahedral sites in ZnGa 2 O 4 nanocrystals. The crystal field parameter D q of 418 cm −1 and the Racah parameters B of 761 cm −1 and C of 3424 cm −1 were determined for tetrahedral Co 2+ ions.

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Available abstract

Transparent ZnO–Ga 2 O 3 –SiO 2 glass-ceramics embedded with Co 2+ :ZnGa 2 O 4 nanocrystals were fabricated by the sol–gel method. X-ray diffraction, infrared spectroscopy and high-resolution transmission electron microscopy showed that the resulting material is composed of an amorphous silicate network and single-crystalline ZnGa 2 O 4 particles. Analysis of the absorption and luminescence properties indicates that Co ions are trapped in the crystalline phase and located in the tetrahedral sites in ZnGa 2 O 4 nanocrystals. The crystal field parameter D q of 418 cm −1 and the Racah parameters B of 761 cm −1 and C of 3424 cm −1 were determined for tetrahedral Co 2+ ions.

Key concepts: Materials science, Nanocrystal, Amorphous solid, Luminescence, Transmission electron microscopy, Absorption spectroscopy, Ceramic, Absorption (acoustics)

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