Synthesis and optical properties of transparent ZnO–Ga2O3–SiO2glass-ceramics embedded with cobalt-doped nanocrystals
Xiulan Duan, Dongsheng Yuan, Xiu Feng Cheng, Fapeng Yu, Zhiqiang Liu, Xiangze Zhang
Abstract
Xiulan Duan, Dongsheng Yuan, Xiu Feng Cheng, Fapeng Yu, Zhiqiang Liu, Xiangze Zhang
Abstract
Transparent ZnO–Ga 2 O 3 –SiO 2 glass-ceramics embedded with Co 2+ :ZnGa 2 O 4 nanocrystals were fabricated by the sol–gel method. X-ray diffraction, infrared spectroscopy and high-resolution transmission electron microscopy showed that the resulting material is composed of an amorphous silicate network and single-crystalline ZnGa 2 O 4 particles. Analysis of the absorption and luminescence properties indicates that Co ions are trapped in the crystalline phase and located in the tetrahedral sites in ZnGa 2 O 4 nanocrystals. The crystal field parameter D q of 418 cm −1 and the Racah parameters B of 761 cm −1 and C of 3424 cm −1 were determined for tetrahedral Co 2+ ions.
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Transparent ZnO–Ga 2 O 3 –SiO 2 glass-ceramics embedded with Co 2+ :ZnGa 2 O 4 nanocrystals were fabricated by the sol–gel method. X-ray diffraction, infrared spectroscopy and high-resolution transmission electron microscopy showed that the resulting material is composed of an amorphous silicate network and single-crystalline ZnGa 2 O 4 particles. Analysis of the absorption and luminescence properties indicates that Co ions are trapped in the crystalline phase and located in the tetrahedral sites in ZnGa 2 O 4 nanocrystals. The crystal field parameter D q of 418 cm −1 and the Racah parameters B of 761 cm −1 and C of 3424 cm −1 were determined for tetrahedral Co 2+ ions.
Key concepts: Materials science, Nanocrystal, Amorphous solid, Luminescence, Transmission electron microscopy, Absorption spectroscopy, Ceramic, Absorption (acoustics)