ScholarLens Back to search
1980•Journal of the Chemical Society Dalton TransactionsRequires access

Kinetics of oxidation of aquairon(2+) by iodate in dilute perchloric acid solution

W. C. E. Higginson, Davina A. McCarthy

Open publisher page 4 citations

Abstract

The kinetics of oxidation of aquairon(2+) by iodate in dilute perchloric acid have been studied at 35 °C in the presence of allyl alcohol, thus avoiding catalysis by the molecular iodine normally formed in this reaction. Overall, the reaction is 4Fe2++ IO3–→ 4Fe3++ II, followed by rapid removal of II by its reaction with allyl alcohol. The kinetic equation is –d[Fe2+]/dt= 4k1(k2+k3[Fe2+])[Fe2+][IO3–]/(k–1+k2+k3[Fe2+]). Aspects of the reaction mechanism are discussed.

About this research paper

What this paper is about

The kinetics of oxidation of aquairon(2+) by iodate in dilute perchloric acid have been studied at 35 °C in the presence of allyl alcohol, thus avoiding catalysis by the molecular iodine normally formed in this reaction. Overall, the reaction is 4Fe2++ IO3–→ 4Fe3++ II, followed by rapid removal of II by its reaction with allyl alcohol. The kinetic equation is –d[Fe2+]/dt= 4k1(k2+k3[Fe2+])[Fe2+][IO3–]/(k–1+k2+k3[Fe2+]). Aspects of the reaction mechanism are discussed.

Why it matters

OpenAlex reports 4 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The kinetics of oxidation of aquairon(2+) by iodate in dilute perchloric acid have been studied at 35 °C in the presence of allyl alcohol, thus avoiding catalysis by the molecular iodine normally formed in this reaction. Overall, the reaction is 4Fe2++ IO3–→ 4Fe3++ II, followed by rapid removal of II by its reaction with allyl alcohol. The kinetic equation is –d[Fe2+]/dt= 4k1(k2+k3[Fe2+])[Fe2+][IO3–]/(k–1+k2+k3[Fe2+]). Aspects of the reaction mechanism are discussed.

Key concepts: Perchloric acid, Iodate, Chemistry, Kinetics, Alcohol, Inorganic chemistry, Catalysis, Iodine

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Kinetics of oxidation of aquairon(2+) by iodate in dilute perchloric acid solution — Research Paper | ScholarLens