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Tetrakis(trifluormethylisocyanid)nickel, Ni(CNCF3)4, und Bis[μ‐(trifluormethylisocyanid)‐(η‐cyclopentadienyl)nickel], [Ni(μ‐CNCF3)(η‐C5H5]2

Dieter Lentz

Abstract

Abstract Tetrakis(trifluormethylisocyanid)nickel (3) bildet sich in guten Ausbeuten bei der Reaktion von Tetracarbonylnickel (1) mit Trifluormethylisocyanid (2). 3 ist der erste homoleptische Trifluormethylisocyanidkomplex. Der zweikernige Komplex [Ni(μ‐CNCF3)(η‐C5H5)]2 (5) entsteht aus 3 und Bis(η‐cyclopentadienyl)nickel (4). Seine spektroskopischen Daten beweisen das alleinige Vorliegen des Trifluormethylisocyanid‐überbrückten Isomeren.

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Key concepts: Nickel, Chemistry, Cyclopentadienyl complex, Nickel compounds, Catalysis, Organic chemistry