Mass Spectrometry of Oligosaccharides(I)—Formation of the [M+Nh4]+Ion of Oligosaccharides in Fast Atom Bombardment Mass Spectrometry
Panl Yuan-Jiang, Zhai Jian-Jun, Yaozu Chen
Abstract
Panl Yuan-Jiang, Zhai Jian-Jun, Yaozu Chen
Abstract
In positive-ion fast atom bombardment (FAB) mass spectrometry, when oligosaccharides are mixed with an appropriate amount of NH4Cl, a highly abundant [M+NH4]+ peak appears in FAB mass spectra. From the adduct ion [M+NH4]+, the molecular weights of oligosaccharides can be determined definitively. This technique may especially be applied to analyze the mixture of oligosaccharides.
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In positive-ion fast atom bombardment (FAB) mass spectrometry, when oligosaccharides are mixed with an appropriate amount of NH4Cl, a highly abundant [M+NH4]+ peak appears in FAB mass spectra. From the adduct ion [M+NH4]+, the molecular weights of oligosaccharides can be determined definitively. This technique may especially be applied to analyze the mixture of oligosaccharides.
Key concepts: Fast atom bombardment, Chemistry, Mass spectrometry, Ion, Adduct, Mass spectrum, Mass, Analytical Chemistry (journal)