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1972•Journal of the American Oil Chemists SocietyRequires access

Kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution

G.T. Clegg, Pierre Winter

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Abstract

Abstract Kinetic data have been obtained for the reaction between chlorine and oleic acid in carbon tetrachloride solution by measuring the chlorine depletion and hydrogen chloride production as a function of residence time in a rod‐like flow system. The data are well correlated by a kinetic model incorporating parallel, second‐order addition and substitution reactions. Measured reaction rates are an order of magnitude less than those reported in a previous investigation which neglected substitution reactions.

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Abstract Kinetic data have been obtained for the reaction between chlorine and oleic acid in carbon tetrachloride solution by measuring the chlorine depletion and hydrogen chloride production as a function of residence time in a rod‐like flow system. The data are well correlated by a kinetic model incorporating parallel, second‐order addition and substitution reactions. Measured reaction rates are an order of magnitude less than those reported in a previous investigation which neglected substitution reactions.

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Available abstract

Abstract Kinetic data have been obtained for the reaction between chlorine and oleic acid in carbon tetrachloride solution by measuring the chlorine depletion and hydrogen chloride production as a function of residence time in a rod‐like flow system. The data are well correlated by a kinetic model incorporating parallel, second‐order addition and substitution reactions. Measured reaction rates are an order of magnitude less than those reported in a previous investigation which neglected substitution reactions.

Key concepts: Chlorine, Carbon tetrachloride, Hydrogen chloride, Chemistry, Oleic acid, Kinetics, Inorganic chemistry, Order of reaction

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