1993Phosphorus, sulfur, and silicon and the related elementsRequires access

INVESTIGATION OF THE REACTION BETWEEN DIALKYLPHOSPHINES AND CARBON TETRACHLORIDE. PART I

Piotr Majewski

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Abstract

The model reaction between diethylphosphine (3a) and carbon tetrachloride leading to chloro-(chloromethyl)diethylphosphonium chloride (5a) and chlorodiethylphosphine (4a) as the final product has been found to involve iethyltrichloromethylphosphine (la) and diethylphosphine hydrogen chloride (6a) as the crucial intermediates. Process of the transformation of these compounds into the final products is a subject of our consideration.

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What this paper is about

The model reaction between diethylphosphine (3a) and carbon tetrachloride leading to chloro-(chloromethyl)diethylphosphonium chloride (5a) and chlorodiethylphosphine (4a) as the final product has been found to involve iethyltrichloromethylphosphine (la) and diethylphosphine hydrogen chloride (6a) as the crucial intermediates. Process of the transformation of these compounds into the final products is a subject of our consideration.

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Available abstract

The model reaction between diethylphosphine (3a) and carbon tetrachloride leading to chloro-(chloromethyl)diethylphosphonium chloride (5a) and chlorodiethylphosphine (4a) as the final product has been found to involve iethyltrichloromethylphosphine (la) and diethylphosphine hydrogen chloride (6a) as the crucial intermediates. Process of the transformation of these compounds into the final products is a subject of our consideration.

Key concepts: Carbon tetrachloride, Hydrogen chloride, Tetrachloride, Chemistry, Chloride, Product (mathematics), Hydrogen, Carbon fibers

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INVESTIGATION OF THE REACTION BETWEEN DIALKYLPHOSPHINES AND CARBON TETRACHLORIDE. PART I — Research Paper | ScholarLens