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2007•Russian Journal of Physical Chemistry ARequires access

The enthalpy of formation of fullerene fluoride C60F18 and the C-F bond energy

T. S. Papina, V.A. Lukyanova, Alexey A. Goryunkov, Ilya N. Ioffe, I.V. Goldt, A. G. Buyanovskaya, N. M. Kabaeva, Л.Н. Сидоров

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Abstract

The enthalpy of combustion of crystalline fullerene fluoride C 60 F 18 was determined in an isoperibolic calorimeter with a rotating platinized bomb, and the enthalpy of formation of the compound was calculated. The enthalpy of sublimation of C 60 F 18 measured earlier was used to calculate the enthalpy of formation of fullerene fluoride in the gas phase and the mean enthalpy of dissociation of C-F bonds in this compound.

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What this paper is about

The enthalpy of combustion of crystalline fullerene fluoride C 60 F 18 was determined in an isoperibolic calorimeter with a rotating platinized bomb, and the enthalpy of formation of the compound was calculated. The enthalpy of sublimation of C 60 F 18 measured earlier was used to calculate the enthalpy of formation of fullerene fluoride in the gas phase and the mean enthalpy of dissociation of C-F bonds in this compound.

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Available abstract

The enthalpy of combustion of crystalline fullerene fluoride C 60 F 18 was determined in an isoperibolic calorimeter with a rotating platinized bomb, and the enthalpy of formation of the compound was calculated. The enthalpy of sublimation of C 60 F 18 measured earlier was used to calculate the enthalpy of formation of fullerene fluoride in the gas phase and the mean enthalpy of dissociation of C-F bonds in this compound.

Key concepts: Enthalpy of atomization, Enthalpy, Sublimation (psychology), Enthalpy of vaporization, Standard enthalpy of formation, Chemistry, Standard enthalpy of reaction, Enthalpy change of solution

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