Thermochemistry
Michael Clugston, Malcolm Stewart, Fabrice Birembaut
Abstract
Michael Clugston, Malcolm Stewart, Fabrice Birembaut
Abstract
This chapter focuses on thermochemistry. It starts with enthalpy change which is the heat added to a system at constant pressure. The reaction is considered endothermic if heat is taken, while it would be exothermic if heat is given out. As the chapter shows, a calorimeter can be used to measure enthalpy changes. According to Hess's law, the standard enthalpy change for a reaction is independent of the route taken from reactants to products. Atomization enthalpy, on the other hand, is the standard enthalpy change accompanying the formation of a gaseous atom from either a solid or a gas containing molecule. Finally, the chapter explains bond enthalpy, solution enthalpy, and hydration enthalpy as well.
A significance statement is not available in the OpenAlex record.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
This chapter focuses on thermochemistry. It starts with enthalpy change which is the heat added to a system at constant pressure. The reaction is considered endothermic if heat is taken, while it would be exothermic if heat is given out. As the chapter shows, a calorimeter can be used to measure enthalpy changes. According to Hess's law, the standard enthalpy change for a reaction is independent of the route taken from reactants to products. Atomization enthalpy, on the other hand, is the standard enthalpy change accompanying the formation of a gaseous atom from either a solid or a gas containing molecule. Finally, the chapter explains bond enthalpy, solution enthalpy, and hydration enthalpy as well.
Key concepts: Thermochemistry, Enthalpy of atomization, Enthalpy, Enthalpy of vaporization, Standard enthalpy of reaction, Standard enthalpy of formation, Exothermic reaction, Endothermic process