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Gasoline sulfur control may be required. Gasoline production and sulfur content

Eugene I. Motte

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Abstract

An analysis of the comparative costs for reducing the sulfur content of current unleaded gasoline supplies in the U.S. to avoid sulfate pollution in use with three-way exhaust-gas catalysts, indicates that hydrodesulfurization of the fluid catalytic cracker (FCC) feed, which is mainly 316/sup 0/-538/sup 0/C straight-run gas oil containing 1000-4000 ppm sulfur, would cost a total of $3-$5 billion and would reduce the sulfur content of the product by 400-700 ppm. Hydrotreating of the heavy (intermediate) fraction of the FCC product gasoline to 1 ppm sulfur, followed by reforming to raise the octane rating, would cost about $48 million but would reduce total gasoline production by 5.Vertical Bar3<. Desulfurization of the 21/sup 0/-93/sup 0/C straight-run light naphtha fraction would cost $11 million, with no loss of gasoline production but with an over-all sulfur-content reduction of only 10-30 ppm. The cost of desulfurization is thus $0.04-$0.06/gal/1000 ppm sulfur reduction for the FCC feed or the FCC product gasoline, and $0.10-$0.30/gal/1000 ppm for the light naphtha. Finished unleaded gasoline with 200 ppm sulfur should be obtainable from FCC gasoline for $3-$5 billion; a similar fuel with 100 ppm sulfur should be obtainable from FCC gasoline and light naphtha for $4-$6 billion.

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An analysis of the comparative costs for reducing the sulfur content of current unleaded gasoline supplies in the U.S. to avoid sulfate pollution in use with three-way exhaust-gas catalysts, indicates that hydrodesulfurization of the fluid catalytic cracker (FCC) feed, which is mainly 316/sup 0/-538/sup 0/C straight-run gas oil containing 1000-4000 ppm sulfur, would cost a total of $3-$5 billion and would reduce the sulfur content of the product by 400-700 ppm. Hydrotreating of the heavy (intermediate) fraction of the FCC product gasoline to 1 ppm sulfur, followed by reforming to raise the octane rating, would cost about $48 million but would reduce total gasoline production by 5.Vertical Bar3<. Desulfurization of the 21/sup 0/-93/sup 0/C straight-run light naphtha fraction would cost $11 million, with no loss of gasoline production but with an over-all sulfur-content reduction of only 10-30 ppm. The cost of desulfurization is thus $0.04-$0.06/gal/1000 ppm sulfur reduction for the FCC feed or the FCC product gasoline, and $0.10-$0.30/gal/1000 ppm for the light naphtha. Finished unleaded gasoline with 200 ppm sulfur should be obtainable from FCC gasoline for $3-$5 billion; a similar fuel with 100 ppm sulfur should be obtainable from FCC gasoline and light naphtha for $4-$6 billion.

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Available abstract

An analysis of the comparative costs for reducing the sulfur content of current unleaded gasoline supplies in the U.S. to avoid sulfate pollution in use with three-way exhaust-gas catalysts, indicates that hydrodesulfurization of the fluid catalytic cracker (FCC) feed, which is mainly 316/sup 0/-538/sup 0/C straight-run gas oil containing 1000-4000 ppm sulfur, would cost a total of $3-$5 billion and would reduce the sulfur content of the product by 400-700 ppm. Hydrotreating of the heavy (intermediate) fraction of the FCC product gasoline to 1 ppm sulfur, followed by reforming to raise the octane rating, would cost about $48 million but would reduce total gasoline production by 5.Vertical Bar3<. Desulfurization of the 21/sup 0/-93/sup 0/C straight-run light naphtha fraction would cost $11 million, with no loss of gasoline production but with an over-all sulfur-content reduction of only 10-30 ppm. The cost of desulfurization is thus $0.04-$0.06/gal/1000 ppm sulfur reduction for the FCC feed or the FCC product gasoline, and $0.10-$0.30/gal/1000 ppm for the light naphtha. Finished unleaded gasoline with 200 ppm sulfur should be obtainable from FCC gasoline for $3-$5 billion; a similar fuel with 100 ppm sulfur should be obtainable from FCC gasoline and light naphtha for $4-$6 billion.

Key concepts: Gasoline, Naphtha, Hydrodesulfurization, Sulfur, Octane rating, Flue-gas desulfurization, Fraction (chemistry), Chemistry

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