2003Acta Scientiarum Naturalium Universitatis SunyatseniRequires access

PREPARATION AND CHARACTERIZATION OF POLY[STYRENE-co-4-(2-PHENYLTHIOETHYLTHIOMETHYL)STYRENE]

Bi-yaoWu, Chuan-junLiu, Shu-xianZhang

Open publisher page 0 citations

Abstract

Sulfur-containing monomers have received special interest from researchers because of their outstanding optical performance. Using the reaction between 2-phenylthioethyl-l-mercaptan and p-chloromethylstyrene, a new vinyl monomer 4-(2-phenylthioethylthiomethyl)styrene (PTETMSt) was synthesized. Its structure was characterized by FT-IR and NMR.Copolymerization of styrene and PTETMSt was investigated. The data show that poly(styrene-co-PTETMSt) has higher refractive index, lower density and percentage of water absorption. The copolymer can be used on optical materials.

About this research paper

What this paper is about

Sulfur-containing monomers have received special interest from researchers because of their outstanding optical performance. Using the reaction between 2-phenylthioethyl-l-mercaptan and p-chloromethylstyrene, a new vinyl monomer 4-(2-phenylthioethylthiomethyl)styrene (PTETMSt) was synthesized. Its structure was characterized by FT-IR and NMR.Copolymerization of styrene and PTETMSt was investigated. The data show that poly(styrene-co-PTETMSt) has higher refractive index, lower density and percentage of water absorption. The copolymer can be used on optical materials.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Sulfur-containing monomers have received special interest from researchers because of their outstanding optical performance. Using the reaction between 2-phenylthioethyl-l-mercaptan and p-chloromethylstyrene, a new vinyl monomer 4-(2-phenylthioethylthiomethyl)styrene (PTETMSt) was synthesized. Its structure was characterized by FT-IR and NMR.Copolymerization of styrene and PTETMSt was investigated. The data show that poly(styrene-co-PTETMSt) has higher refractive index, lower density and percentage of water absorption. The copolymer can be used on optical materials.

Key concepts: Copolymer, Styrene, Monomer, Polymer chemistry, Characterization (materials science), Materials science, Chemistry, Polymer

Related papers

Back to paper searchBrowse research topicsOriginal source
PREPARATION AND CHARACTERIZATION OF POLY[STYRENE-co-4-(2-PHENYLTHIOETHYLTHIOMETHYL)STYRENE] — Research Paper | ScholarLens