PREPARATION AND CHARACTERIZATION OF POLY[STYRENE-co-4-(2-PHENYLTHIOETHYLTHIOMETHYL)STYRENE]
Bi-yaoWu, Chuan-junLiu, Shu-xianZhang
Abstract
Bi-yaoWu, Chuan-junLiu, Shu-xianZhang
Abstract
Sulfur-containing monomers have received special interest from researchers because of their outstanding optical performance. Using the reaction between 2-phenylthioethyl-l-mercaptan and p-chloromethylstyrene, a new vinyl monomer 4-(2-phenylthioethylthiomethyl)styrene (PTETMSt) was synthesized. Its structure was characterized by FT-IR and NMR.Copolymerization of styrene and PTETMSt was investigated. The data show that poly(styrene-co-PTETMSt) has higher refractive index, lower density and percentage of water absorption. The copolymer can be used on optical materials.
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Sulfur-containing monomers have received special interest from researchers because of their outstanding optical performance. Using the reaction between 2-phenylthioethyl-l-mercaptan and p-chloromethylstyrene, a new vinyl monomer 4-(2-phenylthioethylthiomethyl)styrene (PTETMSt) was synthesized. Its structure was characterized by FT-IR and NMR.Copolymerization of styrene and PTETMSt was investigated. The data show that poly(styrene-co-PTETMSt) has higher refractive index, lower density and percentage of water absorption. The copolymer can be used on optical materials.
Key concepts: Copolymer, Styrene, Monomer, Polymer chemistry, Characterization (materials science), Materials science, Chemistry, Polymer