Low-cost options for upgrading light straight run naphtha

Of the many alternatives available for gasoline pool octane improvement, light straight run naphtha isomerization is among the most attractive. Recent catalyst and process developments have improved the cost effectiveness and flexibility of the Penex process for achieving octane improvement. Two new commercial catalysts have been developed, the first obtains maximum once-through octane on desulfurized feeds in new or revamped units, the second allows operation at feed sulfur levels above 100 ppm. New process developments permit low cost product recycle to achieve maximum octane. An isomerization unit may be designed for once-through operation initially with postponed investment for recycle operation.