1989•Journal of the Korean Chemical SocietyRequires access

A Selective Oxidation of Tetraline by Chromium (VI) Compounds (I)

Sun‐Kun Bae, Sang‐Bong Lee, Dae-Chul Park, Kyu-Wan Lee

Abstract

Liquid phase oxidation of tetralin with clean air were carried out utilizing complexes composed of various heterocyclic base and CrO in N,N-dialkylamides. In the CrO-N,N-dialkylacetamide complex catalyzed oxidations of tetralin at 90C, the maximum conversion of tetralin to the products and selectivity of -tetralone were 35.2% and 96.1%, respectively. Under this condition, however, negligible amount of -tetralol was determined.

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Key concepts: Tetralin, Tetralone, Chemistry, Chromium, Selectivity, Catalysis, Base (topology), Organic chemistry