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Oxidation of silicide coatings on niobium and its alloys VN-2 and VN-3

Tsirlin, Anatoly V. Kasatkin, A.V. Byalobzheskii

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Abstract

The kinetics of silicized Nb alloy oxidation were investigated. It was found that the relatively low heat resistance of silicide coatings on niobium and VN-2 and VN-3 alloys at 1200 to 1400/sup 0/C is due to the formation of the higher niobium oxide Nb/sub 2/O/sub 5/ during oxidation, in addition to amorphous silica. The stage-by-stage character of the oxidation of coated samples is associated with the formation (under the oxide film) of a heterophase zone comprising a mixture of higher and lower niobium silicides. The presence of microcracks has a considerable influence on the oxidation process at 1400/sup 0/C.

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The kinetics of silicized Nb alloy oxidation were investigated. It was found that the relatively low heat resistance of silicide coatings on niobium and VN-2 and VN-3 alloys at 1200 to 1400/sup 0/C is due to the formation of the higher niobium oxide Nb/sub 2/O/sub 5/ during oxidation, in addition to amorphous silica. The stage-by-stage character of the oxidation of coated samples is associated with the formation (under the oxide film) of a heterophase zone comprising a mixture of higher and lower niobium silicides. The presence of microcracks has a considerable influence on the oxidation process at 1400/sup 0/C.

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Available abstract

The kinetics of silicized Nb alloy oxidation were investigated. It was found that the relatively low heat resistance of silicide coatings on niobium and VN-2 and VN-3 alloys at 1200 to 1400/sup 0/C is due to the formation of the higher niobium oxide Nb/sub 2/O/sub 5/ during oxidation, in addition to amorphous silica. The stage-by-stage character of the oxidation of coated samples is associated with the formation (under the oxide film) of a heterophase zone comprising a mixture of higher and lower niobium silicides. The presence of microcracks has a considerable influence on the oxidation process at 1400/sup 0/C.

Key concepts: Niobium, Silicide, Materials science, Oxide, Alloy, Niobium oxide, Metallurgy, Amorphous solid

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