Oxidation of silicide coatings on niobium and its alloys VN-2 and VN-3
Tsirlin, Anatoly V. Kasatkin, A.V. Byalobzheskii
Abstract
Tsirlin, Anatoly V. Kasatkin, A.V. Byalobzheskii
Abstract
The kinetics of silicized Nb alloy oxidation were investigated. It was found that the relatively low heat resistance of silicide coatings on niobium and VN-2 and VN-3 alloys at 1200 to 1400/sup 0/C is due to the formation of the higher niobium oxide Nb/sub 2/O/sub 5/ during oxidation, in addition to amorphous silica. The stage-by-stage character of the oxidation of coated samples is associated with the formation (under the oxide film) of a heterophase zone comprising a mixture of higher and lower niobium silicides. The presence of microcracks has a considerable influence on the oxidation process at 1400/sup 0/C.
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The kinetics of silicized Nb alloy oxidation were investigated. It was found that the relatively low heat resistance of silicide coatings on niobium and VN-2 and VN-3 alloys at 1200 to 1400/sup 0/C is due to the formation of the higher niobium oxide Nb/sub 2/O/sub 5/ during oxidation, in addition to amorphous silica. The stage-by-stage character of the oxidation of coated samples is associated with the formation (under the oxide film) of a heterophase zone comprising a mixture of higher and lower niobium silicides. The presence of microcracks has a considerable influence on the oxidation process at 1400/sup 0/C.
Key concepts: Niobium, Silicide, Materials science, Oxide, Alloy, Niobium oxide, Metallurgy, Amorphous solid