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MILLIMETER WAVE JET SPECTROSCOPY OF CARBON MONOXIDE-CONTAINING VAN DER WAALS COMPLEXES
Kaley A. Walker, A. R. W. McKellar
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Abstract
A new pulsed supersonic jet millimeter wave spectrometer has been constructed at NRC. In similar instruments of this $type^{a,b}$ the supersonic jet is injected perpendicular to the millimeter wave radiation. We have found that there is an increase in the sensitivity of our spectrometer by introducing the expansion parallel to the millimeter wave radiation. As a test of this new spectrometer, the pure rotational spectra of KrCO and XeCO, b-type transitions of 5 isotopomers of $Kr^{12} C^{16} O$ and 6 isotopomers of $Xe^{12} C^{16} O$ have been detected between 75 and 100 GHz, including those of species containing rare gas atoms of low natural abundance ${^{80} Kr(2.25%)$ and $^{130} Xe(4.1%)}$.