Low-FeO Ordinary Chondrites: A Nebular Origin and New Chondrite Parent Body
T. J. McCoy, K. Keil, EDWARD R. D. SCOTT, G. K. Benedix, Arthur J. Ehlmann, T. K. Mayeda, R. N. Clayton
Abstract
T. J. McCoy, K. Keil, EDWARD R. D. SCOTT, G. K. Benedix, Arthur J. Ehlmann, T. K. Mayeda, R. N. Clayton
Abstract
We have studied five meteorites [Wray (a), Cerro 10s Calvos, Willaroy, Moorabie and Suwahib (Buwah)] which differ from other chondritic meteorites and appear to form a new group. They are closely related to ordinary chondrites, but have lower FeO in the mafic silicates than H chondrites. Furthermore, their oxygen isotopic compositions are intermediate between E and H chondrites; they have highly variable metal contents, low Co concentrations in kamacite, and high troilite contents. The differences between low-FeO and H, L and LL chondrites appear to have been established in the solar nebula, not through parent body processes. Low-FeO chondrites did not originate on the H chondrite or IIE iron parent bodies, but probably represent a new ordinary chondrite parent body. PROPERTIES The low-FeO contents of Cerro 10s Calvos, Willaroy, Moorabie and Suwahib (Buwah) have been noted by several authors [e.g.,1,2] and these meteorites have been examined in detail [2]. We recently recognized the low-FeO nature of Wray (a) [3] and here report on our comparative studies. Classification Low-FeO chondrites are weakly metamorphosed and exhibit wide ranges of shock and weathering. Classification of petrologic types, shock stages [4] and weathering [5] are as follows: Wray (a): 4, S4, W1; Cerro 10s Calvos: 4, S2, W3; Willaroy: 3.8, S2, W4; Moorabie: 3.9, S4, Wl ; and Suwahib (Buwah): 3.8, S5, W1. MaJic Silicate Compositions Fa concentrations in low-FeO chondrites (Fa12.8-15.3) are below those of H chondrites (Fa16.9-20.4). Low-Ca pyroxene compositions are intermediate between H and E chondrites. Metal and Troilite Abundances Fe,Ni metal abundances in low-FeO chondrites are highly variable (1 1.2-19.4 wt.%, weathering corrected) and overlap with H and L chondrites. Troilite contents in the mildly weathered Moorabie (9.1 wt.%) and Suwahib (Buwah) (8.6 wt.%) are higher than found in any ordinary chondrite [6], although analyses of these meteorites by [7] suggest normal OC abundances of troilite. Sampling heterogeneity may be responsible. Cobalt in Kamacite The Co concentrations in kamacite of low-FeO chondrites (0.30-0.45 wt.% [2, this work]) are near or lower than those in H chondrites (0.44-0.51 wt.% [8]). Chondrule Sizes Low-FeO chondrites have mean chondrule diameters around 400 pm w r a y (a), Cerro 10s Calvos, Willaroy] and 600 pm [Moorabie, Suwahib (Buwah)]. These values are close to H (-300 pm) and L (-600-800 pm) chondrites [9]. The poorly constrained ranges of chondrule sizes in H, L and LL chondrites and large standard deviations for chondrule sizes in low-FeO chondrites suggest that this parameter is unreliable for establishing group membership. Oxygen Isotopes The A 1 7 0 values for low-FeO chondrites (0.32-0.87%0 [10,11]) are less than or equal to H chondrites (0.73B.09%0,[10]). Moorabie and Suwahib (Buwah), which have slightly larger chondrules, also have higher A17O. Figure 1 plots the compositions of lowFeO chondrites, along with the fields for H, L, LL and E chondrites. WASSON et al. [2] suggested that Willaroy & Cerro 10s Calvos and Suwahib (Buwah) & Moorabie are H and L chondrites, respectively, that were incorporated into, and partially equilibrated with, aubritic material, primarily because their study of Cumberland Falls chondritic inclusions indicated formation by this mechanism. Low-FeO chondrites also lack the high siderophile abundances of Netschaevo, which [12] called HH chondritic material based on extrapolation of H-L-LL trends. Because of the lack of definitive evidence for reduction (e.g., Fs>Fa) or a reducing host, high troilite contents, and short diffusion distances for oxygen in type 5 ordinary chondrites [lo], we suggest nebular processes produced the low-FeO concentrations. O Lunar and Planetary Institute Provided by the NASA Astrophysics Data System 866 LPSCXYV LOW-FeO CHONDRITES
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We have studied five meteorites [Wray (a), Cerro 10s Calvos, Willaroy, Moorabie and Suwahib (Buwah)] which differ from other chondritic meteorites and appear to form a new group. They are closely related to ordinary chondrites, but have lower FeO in the mafic silicates than H chondrites. Furthermore, their oxygen isotopic compositions are intermediate between E and H chondrites; they have highly variable metal contents, low Co concentrations in kamacite, and high troilite contents. The differences between low-FeO and H, L and LL chondrites appear to have been established in the solar nebula, not through parent body processes. Low-FeO chondrites did not originate on the H chondrite or IIE iron parent bodies, but probably represent a new ordinary chondrite parent body. PROPERTIES The low-FeO contents of Cerro 10s Calvos, Willaroy, Moorabie and Suwahib (Buwah) have been noted by several authors [e.g.,1,2] and these meteorites have been examined in detail [2]. We recently recognized the low-FeO nature of Wray (a) [3] and here report on our comparative studies. Classification Low-FeO chondrites are weakly metamorphosed and exhibit wide ranges of shock and weathering. Classification of petrologic types, shock stages [4] and weathering [5] are as follows: Wray (a): 4, S4, W1; Cerro 10s Calvos: 4, S2, W3; Willaroy: 3.8, S2, W4; Moorabie: 3.9, S4, Wl ; and Suwahib (Buwah): 3.8, S5, W1. MaJic Silicate Compositions Fa concentrations in low-FeO chondrites (Fa12.8-15.3) are below those of H chondrites (Fa16.9-20.4). Low-Ca pyroxene compositions are intermediate between H and E chondrites. Metal and Troilite Abundances Fe,Ni metal abundances in low-FeO chondrites are highly variable (1 1.2-19.4 wt.%, weathering corrected) and overlap with H and L chondrites. Troilite contents in the mildly weathered Moorabie (9.1 wt.%) and Suwahib (Buwah) (8.6 wt.%) are higher than found in any ordinary chondrite [6], although analyses of these meteorites by [7] suggest normal OC abundances of troilite. Sampling heterogeneity may be responsible. Cobalt in Kamacite The Co concentrations in kamacite of low-FeO chondrites (0.30-0.45 wt.% [2, this work]) are near or lower than those in H chondrites (0.44-0.51 wt.% [8]). Chondrule Sizes Low-FeO chondrites have mean chondrule diameters around 400 pm w r a y (a), Cerro 10s Calvos, Willaroy] and 600 pm [Moorabie, Suwahib (Buwah)]. These values are close to H (-300 pm) and L (-600-800 pm) chondrites [9]. The poorly constrained ranges of chondrule sizes in H, L and LL chondrites and large standard deviations for chondrule sizes in low-FeO chondrites suggest that this parameter is unreliable for establishing group membership. Oxygen Isotopes The A 1 7 0 values for low-FeO chondrites (0.32-0.87%0 [10,11]) are less than or equal to H chondrites (0.73B.09%0,[10]). Moorabie and Suwahib (Buwah), which have slightly larger chondrules, also have higher A17O. Figure 1 plots the compositions of lowFeO chondrites, along with the fields for H, L, LL and E chondrites. WASSON et al. [2] suggested that Willaroy & Cerro 10s Calvos and Suwahib (Buwah) & Moorabie are H and L chondrites, respectively, that were incorporated into, and partially equilibrated with, aubritic material, primarily because their study of Cumberland Falls chondritic inclusions indicated formation by this mechanism. Low-FeO chondrites also lack the high siderophile abundances of Netschaevo, which [12] called HH chondritic material based on extrapolation of H-L-LL trends. Because of the lack of definitive evidence for reduction (e.g., Fs>Fa) or a reducing host, high troilite contents, and short diffusion distances for oxygen in type 5 ordinary chondrites [lo], we suggest nebular processes produced the low-FeO concentrations. O Lunar and Planetary Institute Provided by the NASA Astrophysics Data System 866 LPSCXYV LOW-FeO CHONDRITES
Key concepts: Chondrite, Troilite, Kamacite, Meteorite, Chondrule, Ordinary chondrite, Geochemistry, Parent body