2023•Organic LettersOpen access

The Intracavity Extension of 28-Hetero-2,7-naphthiporphyrins in Reactions with Alkylamines

Katarzyna Ślusarek, Jędrzej P. Perdek, Agata Białońska, Rafał A. Grzelczak, Bartosz Szyszko

Abstract

High Resolution Image Download MS PowerPoint Slide The 28-hetero-2,7-naphthiporphyrins reacted with triethylamine and diethylamine to form nonaromatic intracavity-extended macrocycles incorporating naphthodihydro-2 H -pyran, naphthotetrahydropyridine, and naphthopyrrolotetrahydro-1 H -azepine moieties. The new macrocycles were characterized in solution by means of NMR and UV–vis spectroscopy and in the solid state by XRD.

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Key concepts: Chemistry, Extension (predicate logic), Combinatorial chemistry, Programming language, Computer science