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2023•Angewandte ChemieOpen access

Bis(1‐Methyl‐ortho‐Carboranyl)Borane

Manjur O. Akram, John R. Tidwell, Jason L. Dutton, Caleb D. Martin

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Abstract

Abstract The Lewis superacid, bis(1‐methyl‐ortho‐carboranyl)borane, is rapidly accessed in two steps. It is a very effective hydroboration reagent capable of B−H addition to alkenes, alkynes, and cyclopropanes. To date, this is the first identified Lewis superacidic secondary borane and most reactive neutral hydroboration reagent.

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What this paper is about

Abstract The Lewis superacid, bis(1‐methyl‐ortho‐carboranyl)borane, is rapidly accessed in two steps. It is a very effective hydroboration reagent capable of B−H addition to alkenes, alkynes, and cyclopropanes. To date, this is the first identified Lewis superacidic secondary borane and most reactive neutral hydroboration reagent.

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Available abstract

Abstract The Lewis superacid, bis(1‐methyl‐ortho‐carboranyl)borane, is rapidly accessed in two steps. It is a very effective hydroboration reagent capable of B−H addition to alkenes, alkynes, and cyclopropanes. To date, this is the first identified Lewis superacidic secondary borane and most reactive neutral hydroboration reagent.

Key concepts: Hydroboration, Borane, Superacid, Chemistry, Reagent, Boranes, Lewis acids and bases, Medicinal chemistry

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