2023•Journal of Materials Chemistry ARequires access

Probing single-chain conformation and its impact on the optoelectronic properties of donor–accepter conjugated polymers

Zhiqiang Cao, Zhaofan Li, Sara A. Tolba, Gage T. Mason, Miao Xiong, Michael U. Ocheje, Amirhadi Alesadi, Changwoo Do, Kunlun Hong, Ting Lei, Simon Rondeau‐Gagné, Wenjie Xia, Xiaodan Gu

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Abstract

The optoelectronic properties of a given conjugated polymer depend on the chain rigidity and more importantly local chain planarity. The local backbone planarity determines the conjugation length as large twists result in break of conjugation.

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Key concepts: Planarity testing, Conjugated system, Rigidity (electromagnetism), Polymer, Chain (unit), Materials science, Side chain, Polymer chemistry