Pseudo-mono-axial ligand fields that support high energy barriers in triangular dodecahedral Dy( iii ) single-ion magnets

calculations were used to show the apparent difference in the magnetic dynamics of the three complexes, confirming that the pseudo-mono-axial ligand field has an important effect on high-performance SMMs compared with the local symmetry. This study not only presents the highest energy barrier for a triangular dodecahedral SMM but also highlights the enormous potential of the pseudolinear Dy-L ligand field for constructing promising SMMs.