Unveiling the Relationship of Surface Roughness on Superliquid-Repelling Properties with Randomly Distributed Rough Surface Structures

Though superliquid-repelling surfaces are universally important in the fields of fundamental research and industrial production, the understanding and development of these surfaces to impacting liquid droplets remain elusive, especially the changes of wettability states. Surface roughness is required to obtain superliquid-repelling surfaces. However, the effect of surface roughness on the transition of these surfaces’ wettability states is uncertain. Herein, we unveiled the relationship of surface roughness on regulating the wettability states of superliquid-repelling surfaces with randomly distributed rough structures through experiment and calculations. The roughness was controlled via regulating the size of surface rough structures, which were formed by a facile coating method. The results indicated that the surface rough structures could impact the value of the polar component (γ s p ) and then impact the wettability states of superliquid-repelling surfaces. Quantitatively, when the increment of surface roughness was low, the decrement of γ s p was low and the wettability state of the superliquid-repelling surface was superhydrophobicity. When the increment of surface roughness was high, the decrement of γ s p was high and the wettability state of the superliquid-repelling surface converted to superamphiphobicity. The findings will shed light onto the development of superliquid-repelling surfaces in future studies.