Noha Khamis, Guy J. Clarkson, Martin Wills
Abstract
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Six novel Noyori–Ikariya complexes, containing a heterocyclic group at the sulfonyl position, were used as catalysts for the ATH of ketones. Alcohols were formed in high conversion and ee, including ortho -substituted derivatives.
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Six novel Noyori–Ikariya complexes, containing a heterocyclic group at the sulfonyl position, were used as catalysts for the ATH of ketones. Alcohols were formed in high conversion and ee, including ortho -substituted derivatives.
Key concepts: Acetophenone, Transfer hydrogenation, Catalysis, Noyori asymmetric hydrogenation, Chemistry, Enantioselective synthesis, Diamine, Asymmetric hydrogenation