2022Physical Chemistry Chemical PhysicsOpen access

First hyperpolarizability of water in bulk liquid phase: long-range electrostatic effects included via the second hyperpolarizability

Guillaume Le Breton, Oriane Bonhomme, Emmanuel Bénichou, Claire Loison

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Abstract

The molecular first hyperpolarizability β contributes to second-order optical non-linear signals collected from molecular liquids. The second hyperpolarizability γ permits to model how the environment far away from a target molecule impacts its β .

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The molecular first hyperpolarizability β contributes to second-order optical non-linear signals collected from molecular liquids. The second hyperpolarizability γ permits to model how the environment far away from a target molecule impacts its β .

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Available abstract

The molecular first hyperpolarizability β contributes to second-order optical non-linear signals collected from molecular liquids. The second hyperpolarizability γ permits to model how the environment far away from a target molecule impacts its β .

Key concepts: Hyperpolarizability, Chemical physics, Molecule, Phase (matter), Range (aeronautics), Chemistry, Materials science, Computational chemistry

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