1976•Journal of the Chemical Society Chemical CommunicationsRequires access

The geometrical requirements for fluorescent intramolecular exciplex formation and fluorescence quenching

R. Stephen Davidson, Kenneth R. Trethewey

Abstract

From a study of intramolecular exciplex formation by the naphthylalkylamines (I)–(IV) it is concluded that the geometrical requirements for emissive complex formation are greater than those needed for intramolecular fluorescence quenching.

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Key concepts: Intramolecular force, Excimer, Fluorescence, Photochemistry, Quenching (fluorescence), Chemistry, Biophysics, Stereochemistry