2005•Angewandte ChemieRequires access

Transfer of Chirality from (−)‐Sparteine Zinc( II ) (Meth)acrylate Complexes to the Main Chains of Their (Meth)acrylate Polymer Derivatives

Satyasankar Jana, David C. Sherrington

Abstract

Chirale Kette: Die Copolymerisation von (−)-Spartein-zink(II)-dimethacrylat oder -diacrylat mit Styrol- oder 2-Vinylnaphthalin-Monomeren führt nach dem Entfernen der Zinkspartein-Template zu Methacrylsäure- bzw. Acrylsäure-Copolymeren, deren optische Drehung durch die Konfigurationen der Kohlenstoffstereozentren im Polymerrückgrat bestimmt wird (siehe Bild; R=H, Me; Ar=Styryl, 2-Vinylnaphthyl).

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Available abstract

Key concepts: Acrylate, Zinc, Chemistry, Chirality (physics), Meth-, Polymer chemistry, Polymer, Stereochemistry