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ChemInform Abstract: STEREOCHEMICAL CONTROL IN THE CONSTRUCTION OF VICINALLY SUBSTITUTED CYCLOPENTANES AND CYCLOHEXANES. INTRAMOLECULAR CONJUGATE ADDITION OF β‐KETOESTER ANIONS

Gilbert Stork, Jeffrey D. Winkler, Nicholas A. Saccomano

Abstract

Abstract Bei der Behandlung mit alkalischen Katalysatoren werden die ungesättigten Oxo‐Verbindungen (I) in Gemische isomerer Cyclisierungsprodukte (II) und (III) übergeführt und deren jeweilige Anteile in Relation zu den Reaktionsbedingungen bestimmt.

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Available abstract

Key concepts: Cyclohexanes, Cyclopentanes, Conjugate, Chemistry, Intramolecular force, Cyclopentane, Stereochemistry, Medicinal chemistry