1979•ChemInformRequires access

ChemInform Abstract: ASYMMETRIC HYDROGENATION OF PROCHIRAL KETONES BY RHODIUM(I) AND RUTHENIUM(II) CHIRAL DISPHOSPHINE COMPLEXES

Katsutoshi Ohkubo, Masahisa Setoguchi, Kohji Yoshinaga

Abstract

Abstract Als Katalysatoren wurden eingesetzt chirale Rh(I)‐ Komplexe, in situ dargestellt aus [Rh(C2H4)2Cl]2 und (+)‐1,2‐Bis‐[diphenylphosphino]‐propan oder (‐)‐DIOP, sowie ein kristalliner, verbrückter Dimeren‐Komplex von Ru2Cl4[(‐) ‐DIOP]3 (DIOP = 2,3‐O‐Isopropyliden‐2,3‐dihydroxy‐1,4‐bis‐[diphenylphosphino]‐butan).

About this research paper

What this paper is about

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Rhodium, Ruthenium, Asymmetric hydrogenation, Noyori asymmetric hydrogenation, Chemistry, Enantioselective synthesis, Organic chemistry, Catalysis