2000Inorganic ChemistryOpen access

Neocuproine-Extended Porphyrin Coordination Complexes. 2. Spectroscopic Properties of the Metalloporphyrin Derivatives and Investigations into the HOMO Ordering.

Tommaso A. Vannelli, Timothy B. Karpishin

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Abstract

Reaction of Model Nucleobases with the Diaqua(bis(N-methylimidazol-2-yl) ketone)platinum(II) Dication.Synthesis and Structure of the Headto-Tail Isomers of Bis(9-methylguanine-N 7 ) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(1-methylcytosine-N 3 ) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(µ-1-methylthyminato-N 3 ,O 4 )-bis[(bis(N-methylimidazol-2yl) ketone)platinum(II)] Perchlorate, and Bis(µ-1-methyluracilato-N 3 ,O 4 )bis[(bis(N-methylimidazol-2-yl) ketone)platinum(II)] Nitrate Page 3881.In Table 6 the x-coordinates are not given correctly.The data have been corrected in the Cambridge Database and can be taken from there.

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Reaction of Model Nucleobases with the Diaqua(bis(N-methylimidazol-2-yl) ketone)platinum(II) Dication.Synthesis and Structure of the Headto-Tail Isomers of Bis(9-methylguanine-N 7 ) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(1-methylcytosine-N 3 ) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(µ-1-methylthyminato-N 3 ,O 4 )-bis[(bis(N-methylimidazol-2yl) ketone)platinum(II)] Perchlorate, and Bis(µ-1-methyluracilato-N 3 ,O 4 )bis[(bis(N-methylimidazol-2-yl) ketone)platinum(II)] Nitrate Page 3881.In Table 6 the x-coordinates are not given correctly.The data have been corrected in the Cambridge Database and can be taken from there.

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Reaction of Model Nucleobases with the Diaqua(bis(N-methylimidazol-2-yl) ketone)platinum(II) Dication.Synthesis and Structure of the Headto-Tail Isomers of Bis(9-methylguanine-N 7 ) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(1-methylcytosine-N 3 ) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(µ-1-methylthyminato-N 3 ,O 4 )-bis[(bis(N-methylimidazol-2yl) ketone)platinum(II)] Perchlorate, and Bis(µ-1-methyluracilato-N 3 ,O 4 )bis[(bis(N-methylimidazol-2-yl) ketone)platinum(II)] Nitrate Page 3881.In Table 6 the x-coordinates are not given correctly.The data have been corrected in the Cambridge Database and can be taken from there.

Key concepts: Chemistry, Porphyrin, Coordination complex, Photochemistry, Stereochemistry, Organic chemistry, Metal

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Neocuproine-Extended Porphyrin Coordination Complexes. 2. Spectroscopic Properties of the Metalloporphyrin Derivatives and Investigations into the HOMO Ordering. — Research Paper | ScholarLens