2018International Journal of HydromechatronicsOpen access

Thermal performance difference of ideal gas model and van der Waals gas model in gas-loaded accumulator

Shuce Zhang, H. Iwashita, Kazushi SANADA

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Abstract

Real gas that considering intermolecular force and molecular volume shows difference compared with the assumption as ideal. While designing accumulator or quantitatively evaluating working state of accumulator in hydraulic circuit, charged in gas-loaded accumulator, the gas properties involves pressure, temperature and stored energy are assumed by the first law of thermodynamics and gas equation of state. The discrepancy of thermodynamic behaviours of real gas from ideal gas should be highlighted. In this paper, the well-known van der Waals equation was employed as real gas model to compare with ideal gas model. The gas behaviours have shown different trends during compression and expansion by mathematically analysis and being confirmed in both isothermal and adiabatic operations. A detailed pressure deviation between ideal gas model and van der Waals model was displayed.

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What this paper is about

Real gas that considering intermolecular force and molecular volume shows difference compared with the assumption as ideal. While designing accumulator or quantitatively evaluating working state of accumulator in hydraulic circuit, charged in gas-loaded accumulator, the gas properties involves pressure, temperature and stored energy are assumed by the first law of thermodynamics and gas equation of state. The discrepancy of thermodynamic behaviours of real gas from ideal gas should be highlighted. In this paper, the well-known van der Waals equation was employed as real gas model to compare with ideal gas model. The gas behaviours have shown different trends during compression and expansion by mathematically analysis and being confirmed in both isothermal and adiabatic operations. A detailed pressure deviation between ideal gas model and van der Waals model was displayed.

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Available abstract

Real gas that considering intermolecular force and molecular volume shows difference compared with the assumption as ideal. While designing accumulator or quantitatively evaluating working state of accumulator in hydraulic circuit, charged in gas-loaded accumulator, the gas properties involves pressure, temperature and stored energy are assumed by the first law of thermodynamics and gas equation of state. The discrepancy of thermodynamic behaviours of real gas from ideal gas should be highlighted. In this paper, the well-known van der Waals equation was employed as real gas model to compare with ideal gas model. The gas behaviours have shown different trends during compression and expansion by mathematically analysis and being confirmed in both isothermal and adiabatic operations. A detailed pressure deviation between ideal gas model and van der Waals model was displayed.

Key concepts: Ideal gas, Real gas, Ideal gas law, Van der Waals equation, van der Waals force, Accumulator (cryptography), Compressibility factor, Thermodynamics

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Thermal performance difference of ideal gas model and van der Waals gas model in gas-loaded accumulator — Research Paper | ScholarLens