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ChemInform Abstract: ORGANOPLATINUM COMPLEXES RELATED TO THE CYCLODIMERIZATION OF 1,3‐DIENES. REACTIONS OF 2,3‐DIMETHYLBUTA‐1,3‐DIENE AND BUTA‐1,3‐DIENE WITH BIS(CYCLOOCTA‐1,5‐DIENE)PLATINUM OR BIS(ETHYLENE)TRIMETHYLPHOSPHINEPLATINUM

Geoffrey K. Barker, Michael Green, Judith A. K. Howard, John L. Spencer, F. G. A. Stone

Abstract

Abstract Die Reaktion des Pt(O)‐Komplexes (III) mit 2,3‐Dimethylbutadien‐(1,3)"(II) entspricht einer oxidativen 1,4‐Addition des Komplexes an das Dien unter Bildung der Platinacyclopenten‐Verbindung (Ia).

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Key concepts: Diene, Platinum, Chemistry, Medicinal chemistry, Organic chemistry, Catalysis, Natural rubber